![]() 20,21 Therefore, it is necessary to selectively and promptly remove deleterious anions as soon as they penetrate the concrete structure to maintain durability and life span. 19 This deteriorates the life-span of the concrete structures by providing easy penetration paths for other corrosion species.ĭeterioration in performance or structural damage of reinforced concrete structures not only adversely affects safety, but also causes enormous losses to society and the national economy over a long period of time. When the concrete is neutralized and water and air infiltrate, the corrosion of steel and the volume expands, causing cracks in the concrete cover, resulting in loss of the strength and durability of the structure ( eqn (3)). This lowers pH and causes general internal volume expansion in the concentrate. ![]() 16–18 Carbonation occurs by CO 3 2− anions, which originate from carbon dioxide, diffusing into the concrete matrix from the air, reacting with calcium hydroxide to form calcium carbonate. 15 SO 4 2− anion attack occurs by diverse forms drawing on chemical sources, including seawater, acid rain, or combustion gas from industry, leading to destruction of the original properties of concreate ( eqn (2)). 13,14 It can penetrate into concrete in diverse forms drawing on the chemical sources of SO 4 2− anions from the environment, which also promotes corrosion of steel rebar in concrete. 11,12 In this case, the Cl − anion can easily penetrate concrete structures through capillary adsorption, hydrostatic pressure, or diffusion, accelerating steel rebar corrosion ( eqn (1)). Penetration of Cl − anions to reinforced concrete is significantly detrimental, especially for structures near marine environments exposed to high concentrations of salts. 8 Corrosion is generally initiated by electrochemical flow of electrons and ions. ![]() Three major anions from different sources are particularly harmful: chloride (Cl −), sulfate (SO 4 2−), and carbonate (CO 3 2−) anions. 4–6 Nevertheless, corrosion of steel rebar can be readily initiated when passivity is compromised by damage 7 or when the bond between concrete and steel rebar is destroyed by anionic species. 2,3 In general, concrete structures present good durability to corrosion because the structure of concrete presents high alkalinity in the pores of the surrounding concrete, forming a protective, passive layer on the surface of the steel rebar. 1 However, it is always exposed to corrosion, leading to deterioration in concrete structures, which determines their durability and life span, particularly in natural environments. Introduction Building in concrete structures with steel rebar was a remarkable innovation in the construction industry because it adds strength to concrete, providing durability and allowing more specialized designs. ![]() The novel adsorption mechanisms of these CaFe-LDHs-induced crystals and corresponding corrosion protection properties are elucidated drawing on synergy of memory effects and chemical reactions. Furthermore, the steel rebar exposed to an aqueous solution containing the three anionic sources shows a fast corrosion rate (1876.56 × 10 −3 mm per year), which can be remarkably inhibited showing 98.83% of corrosion inhibition efficiency when it is surrounded by those CaFe-LDHs. The synthesized CaFe-LDHs with phase transfer show notable improvement of removal capacity ( Q max) toward Cl − and SO 4 2− over 3.4 times and over 5.69 times, respectably, then those of previous literatures. ![]() It is applied for the removal of Cl −, SO 4 2−, and CO 3 2− anions as well as corrosion inhibition on steel rebar in aqueous solutions. Here, we synthesize CaFe-layered double hydroxide (CaFe-LDHs) by a simple one-step co-precipitation technique and structural modulation by calcination process. Efficient removal of these deleterious anions at the early stage of penetration is crucial to enhance the lifespan and durability of concrete structures. The three anionic species chloride (Cl −), sulfate (SO 4 2−), and carbonate (CO 3 2−), are typical chemical factors that environmentally accelerate failure of concrete structures with steel rebar through long-term exposure. ![]()
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![]() ![]() The man did it all in 25 plate appearances. 938, the eighth-highest ever recorded in a single Fall Classic. and his cumulative game win probability added for that series at. Take a look at the entire shirt collection from our friends over at BreakingT, including the one pictured above.Īll in all, Baseball-Reference puts Ortiz’s championship win probability added at 34%. Louis pitching staff struck him out once in six games. OPS, seventh (Steve Pearce’s 1.167 mark in 2018 has him 10th, by the way). ![]() In slugging percentage, he’s eighth all-time. 760 on-base percentage are each the second-highest ever recorded by a player in a single World Series. On the biggest stage, against a pitching staff that was first in the National League in pitcher wins and fourth in ERA+, Big Papi hit like he was swinging at a beach ball. Louis Cardinals quickly became something I had never seen before, and haven’t since. He was good all year, but this six-game stretch in the Fall Classic against the St. I thought it was inevitable that, no matter the deficit, this team would mount a comeback, and Ortiz was a huge part of that feeling. So, 2013 was the first time I was experiencing a Red Sox playoff run with a consciousness about the game fully-formed.Īll year, it felt like these Red Sox, who led baseball in scoring from innings seven to nine, always came up with that clutch hit. The most I remember about those titles was that my parents would send me to bed by the third inning. When Ortiz was putting this franchise on his back during the 20 World Series, I was still a kid. Thought it’s arguable that this is not the most impressive playoff performance of his career, Ortiz capped an already magical season and playoff with a six-game hitting clinic that stands as one of the best World Series performances ever. Thanks in large part to the man himself, the Boston Red Sox were in the hunt for their third World Series title in nine years. Over the course of 261 hands, Riess played his way to victory at this year's November Nine final table, defeating Vegas-based VIP nightclub host Jay Farber heads-up for the title, bringing this year's Main Event to an emphatic conclusion.A larger than life figure, David Ortiz represented many of the great little things in baseballīy the time the last week of October in 2013 rolled around, David Ortiz was already enjoying a legendary season, one in which he had earned accolades as an All Star as well as a Silver Slugger. ![]() Moreover, he topped a field of 6,352 players who ponied up the $10,000 entry fee to play in what was the eighth-largest tournament in poker history. Sporting a Detroit Lions jersey with the number of his favorite player, wide receiver Calvin Johnson, Riess prevailed over a final table line-up that included two WSOP gold bracelet winners, Amir Lehavot and JC Tran, as well as a wide range of accomplished players representing five different countries. Just one year removed from playing his first live tournament at the Horseshoe Hammond Circuit Main Event, Riess is now a bracelet winner, a World Champion, and 10th on the WOSP all-time money list. The 23-year-old poker pro from Waterford, MI might forever be known as "Riess the Beast" after a tour de force performance in this year's November Nine. Ryan Riess is your 2013 WSOP Main Event Champion, picking up $8,361,570. ![]() ![]() ![]() There are actually two Tao clubs, one uptown and one down town. Given the hefty price tag-you can't get a sushi roll for under $16 or an entree for under $28-this might be more of an expense account joint rather than a regular Saturday night on the town. Tao Club in New York is an Asian bistro and nightclub. Main courses include Atlantic Halibut with Spring Vegetables, Morel Mushrooms and Verjus-Brown Butter Diver Scallops with Rainbow Swiss Chard, Kyoto Carrots and Capers and 30-Day Dry-Aged Ribeye Steak with Rotisserie Leeks & Bearnaise Sauce. Entrees include dishes like Pan Roasted Halibut, Beef Mongolian and Roasted Chicken Chow Mein plus maki of King Salmon with jalapeno and Glazed Tuna with Wild Mushrooms. Help design cocktail menu and new product initiatives assist BOH with operations. Dubbed Tao Downtown, the sprawling 22,000 square foot restaurant boats seating for 400 beneath the Maritime Hotel in the two spaces that previously house Hiro Ballroom and Matsuri.Įxecutive Chef/Partner Ralph Scamardella changed up the menu from the Midtown location, offering a variety of dim sum (chicken gyoza, crispy bao buns, veggie egg rolls), noodles, yakitori and other small plates. TAO Uptown, Nueva York: Consulta 3.709 opiniones sobre TAO Uptown con puntuación 4 de 5 y clasificado en Tripadvisor N.☇69 de 10.128 restaurantes en Nueva York. Tao is an exemplary Asian Fusion restaurant located just south of Central Park and features an acclaimed Dim Sum menu. TAO Group has an impeccable record for throwing world-class. If supping on sushi to the blaring beats of house music sounds like your kind of scene, you'll be thrilled to know that Tao restaurant opens another outpost of their Pan-Asian dynasty this evening. Host your next Special Event at LAVO Singapore in the most dramatic venue at Marina Bay Sands. ![]() ![]() May have an unpleasant aftertaste to some Based on our testing, here are the best whitening toothpastes. We evaluated each toothpaste for its active ingredients, effectiveness, comfort, taste, and before and after teeth color according to the VITA guide. An orthodontist from our Medical Expert Board also reviewed the contents of this article for medical accuracy surrounding dental hygiene and the safety and efficacy of the ingredients in whitening toothpastes. To determine the best whitening toothpaste, we spoke to dentists and home-tested dozens of products from the leading oral care brands. But don’t expect whitening toothpaste to work miracles-he says toothpaste won’t whiten your teeth lighter than their natural shade only bleaching (in a professional setting) can do that. Because whitening toothpastes go beyond simply cleaning your teeth-they work to remove staining-they are often more abrasive than their non-whitening counterparts.Īccording to Steven Morgano, DMD, the chair of the Department of Restorative Dentistry at Rutgers School of Dental Medicine, whitening toothpaste will work if you follow the instructions. Key whitening ingredients include hydrogen peroxide and carbamide peroxide, as well as more abrasive whitening agents such as silica, which works to rub stains off the surface of your teeth. And while you won't find a Relative Dentin Abrasivity (RDA) score for your toothpaste on the label, this number gauges the toothpaste's potential erosive effects on your teeth. Sodium fluoride is a key ingredient in any toothpaste for preventing cavities and strengthening teeth. When shopping for whitening toothpaste, it's important to check the ingredients. “Most toothpastes, whether they're labeled whitening or not, have some kind of a mild abrasive in them to safely remove surface stains from the teeth,” says Edmond Hewlett, DDS, professor at the UCLA School of Dentistry and consumer advisor for the American Dental Association (ADA). ![]() While you brush away plaque and debris and prevent cavities, the addition of whitening ingredients like hydrogen peroxide can also remove stains caused by things like drinking coffee, tea, red wine, or even smoking. Whitening toothpaste is a simple way of getting even more out of the twice-daily habit of brushing your teeth. ![]() ![]() ![]() Feed with a liquid fertiliser monthly during spring, summer and autumn. Can grow outdoors in the shade in warm climates however it must be in a well-draining soil.Ĭare – Water is held in its leaves and stems so make sure to allow the potting mix to dry out between watering. colorred60 : The colour of the ring around the circle is set to 60 red (lighter than pure red). Our experience in this field extends over 13 years ago when Machine Control products. Furthermore, at low temperatures where k << (50 and 60 ☌), the half-width of the emission increases on red-edge excitation to values comparable to those observed at intermediate temperatures. Red Edge Resources was started to fill the void and keep clients running efficiently on their projects. Choose a self-managed or fully managed solution. On red-edge excitation, the emission is dominantly from a single state, the photoselected R state, and hence narrower. Location – Suitable for bright to low indirect light or filtered morning sun indoors. OpenShift delivers a consistent experience across public cloud, on-premise, hybrid cloud, or edge architecture. The best edge control for natural hair and 4c hair with Red One wax Shantee Monfils 673 subscribers Subscribe 13K views 5 years ago Please watch: 'How to EASY, QUICK and LOW MANIPULATION go. Its semi-trailing growth habit means it can even be used in hanging baskets The Peperomia family is a collectors’ delight with a huge range of coloured foliage varieties – start your collection today!įlower Colour – White, small not showy flower Suitable for all hair types, whether your curls are curly, curly or loose, you can use this edge control wax to blend well with the edges of your hair. Excellent indoor and is perfect for beginners. ![]() Botanical name – Peperomia obtusifolia ‘Red Edge’ĭescription – This small plant has dark green spoon shaped leaves with vibrant red edges and red stems. ![]() ![]() ![]() (a,b) IN ( (1,2), (3,4) )ĪNSI date literals (*) Specify date or timestamps using ANSI literals, e.g. (Yes) (*) Not possible with constant values for an IN clause e.g. Yes (*) Not supported with the BETWEEN operator ![]() (Yes) (*) Not supported for >, or between operators (Yes) (*) ORDER BY is not allowed in the window definition Window string aggregates (*) Use string aggregation as a window function Yes (*) Full parallel query support since Postgres 11 Parallel queries (*) The ability to distribute a single query over serveral CPUs Yes (*) When Postgres compatibility is enabled (Yes) (*) No WHERE clause is allowed e.g. Temporal queries (*) Temporal queries allow querying the database (or a single table) to return the data as it was in the past GROUPING SETS (*) Create multiple independent groups with a single GROUP BY query No (*) The crosstab function can be used for this. in a common table expression directly.įiltered aggregates (*) Only include rows in an aggregate based on a condition: avg(salary) filter (where dept_id = 1) Yes (*) Can only be used in a FROM, not e.g. Sometimes also called "table value constructor". Row constructor (*) Use of the VALUES row-constructor wherever a table reference can be used. A CTE name can not be re-used in the same transaction Can not be used in views Can not be used with sub-queries Can not be used with INSERT statements. (Yes) (*) All columns are treated as varchar. Yes (*) DISTINCT is not supported inside a window functionĬTE in a sub-query (*) Use a common table expression in a sub-query, not only as a top level query To get a more in-depth comparison about some of the SQL features compared here, please visit Modern SQL Oracle Postgres SQL Server IBM DB2 MySQL MariaDB Firebird H2 HSQLDB SQLite Feature Features for database administration or deployment are also not the focus of this comparison. This comparison focuses on SQL features that can be used in SQL statements or self-contained SQL scripts that don't requireĪdditional software (e.g. ![]() (The tooltips don't work on Internet Explorer 10 or older versions. Items with (*) have a comment (or explanation) that is shown as a tooltip when hovering the mouse over them ![]() ![]() ![]() Finish up with a soothing balm, menthol is best as it closes pores faster. Then the three pass shave, once with the gain, once perpendicular to the grain and once against the grain. Then apply warm foam, fill a mug with hot water and add the foam on top, shouldn’t take too long to heat up. ![]() Follow up with a hot towel, opens the pores and raises the hairs. This remove dead skin and ensures a smoother shave. I will be using a five steep three pass shave style on three days growth, then again a few days later with the now dull blade to test longevity. I have found in the past that companies that stick to such archaic delivery systems exclusively tend to charge more for the lack of privilege. Rather than, say, a subscription model like Harry’s or Dollar Shave Club. They are both companies that follow the traditional model, selling a handle, cartridges then replacements over time. Their product line in NA covers only the blades and shaving foam, so a little lackluster there. I have been comparing their shave to a variety of firm’s products for the last two months or so, and have fallen in love with one of their products. They offer the full range of blades, more so than most other companies, and sell them at bargain prices, unlike most other companies. ![]() They are responsible for a few tech innovations, and their recent release of the seven bladed razor has endeared them to me, being a fan of the to the bone style shave. They also sell a variety of shaving foams, gels and balms, giving them a bit of an edge over Dorco US in that department.ĭorco are a young firm, a little over 60 years old now. The current product line is exactly as you would expect, a three blade, a four blade and a five blade design. Probably not a good idea to shave with one though. Wilkinson’s Sword were found in 1772, and were famous for their high quality swords. Schick are an old enough firm, founded back in 1926, it is nothing to the age of the bought out UK firm selling the Schick blades. Today is all about the budget options, the Dorco Pace 3 up against the Xtreme 3. But let’s not assume favoritism, there is a reason I split from them after all, and it was mostly due to the rising price of the product. I grew up using their products, disposable and otherwise, so going back to them now is nearly as nostalgic as the Gillette review series. That’s right, it’s Schick! Known as Wilkinson’s Sword in Europe, and one of the power houses of the razor industry. This is a week dedicated to misspelled words and trans Atlantic products. ![]() ![]() Finally a man came over and asked if he could help us. Others were still just standing around talking and we remained ignored. After being told that someone would be with us shortly I was still left waiting after 30 minutes while employee after employee after employee was going to the back to grab their stuff to go home. They closed at 9: 00 and me and three others were sitting there waiting to pick up our repaired devices. I came to pick up my phone around 8: 30 for my 8: 40 pickup time. They were very busy and I understand that, but I saw quite a few employees just standing around talking to each other. ![]() I had a reservation and it took them until 30 minutes after my reservation time to see me. The negatives… the employees working in the store, and there are tons of them, are not efficient. They did a great job on the repair and my phone looks brand new. ![]() When I picked up my phone (repairing a shattered screen) it looked flawless. Want to know why we stopped Or read the history of it? This note explans everything.I’ll start with the positives… the employee that worked with me was very friendly and knowledgeable. This site was set up to track average review times so that developers could plan their releases with a little more confidence. About App Review Timesįrom March 2011 until March 2019, this site aggregated and averaged crowdsourced data on the length of time that app review for the iOS and Mac App Store took.įrom the very start of the App Store, until May 2016 the length of an app review was often very lengthy, causing problems for developers trying to schedule releases or set the expectations of their clients. Fight that urge, and triple-check everything before submitting. The big takeaway: It can be easy to get excited about your app and then submit it for review before the app is 100% ready for prime time. Doesn’t clearly deliver value for users.Other issues that are common causes for rejection include: What are some other reasons an app might be denied?Īccording to Apple, the most common reasons for rejection are minor bugs and privacy concerns. There’s a big distance between an app that handles sensitive financial transactions and an ad-supported Match 3 game, and the app review process is structured accordingly. They also need to be licensed in other jurisdictions they operate including: Colorado, Pennsylvania, Indiana, West Virginia, Iowa, Illinois, Tennessee, Michigan, Virginia, and Nevada.Īnother example: Banking apps. Real-money sportsbook operators in New Jersey are required to be licensed by the state’s Division of Gaming Enforcement, so Apple would, at a minimum, need to verify that DraftKings was properly licensed in New Jersey before approving the app. Ĭonsider DraftKings’ sports betting app in New Jersey. Any apps that involve real-money casino gambling are not going to fall within the review or approval averages cited above due to their unique nature and the particular requirements that Apple has for sportsbook or online casino apps in Michigan, PA, and NJ. It’s also worth noting that there are some classes of apps that are subject to additional review and approval due to issues such as regulatory concerns, specific legal requirements, or specific requirements on the part of Apple.Ī great example: Sports betting apps. The more controversial the app type or genre, the more the approval rate can vary. Roughly 60%, but this number varies significantly by genre and app type. If you think there’s a problem, you can contact the App Store review team. Are there any special instructions connected to your app? Provide full information to avoid any delays in review. ![]() Does your app require user account information? Include this information in your application or you can expect a slower approval turnaround.Does your app require specific settings? Note this in your application or you could face delays.Here are three reasons your app review might be delayed: Maybe your app triggered an extended review, or perhaps something is causing some discussion internally. It happens, but it’s probably not a sign that the average review time is increasing. Has your app review taken more than one day? Q: How long does Apple take to review an app in 2020? A: 24-48 HoursĪpple has improved its review time significantly and reports that 50% of apps are reviewed in 24 hours and over 90% are within 48 hours. ![]() ![]() ![]() This is not a discussion forum to me but rather give/get advice, and you acted ungrateful to say say the least in that thread, low number post account also say some to me! So my knowledge is given as it is and most likely i won't reply you back. I saw you act quite agressive in this thread when you were asking advice about and were given good advice: Thank you!Ĭlick to expand.Now these advices from me! I ask several question here, can someone please go through the post and try to answer all of them. The state on all these ports are Listening - why listen when i don't want or need them to run? - or do I? Are these ports somehow needed for Chrome to work? What Exactly are these ports, how can I determine if i need them or not, and how can i block them? If I can block them, I don't want to ever see them in this list again. I don't want anything going in or out that I don't specify, the PC should look and act as if it's not connected the the internet at all save when I tell it to open Chrome. There are a lot of ports most "duplicates?" Two lsass.exe's many Services.exe's and scvhost.exe's, many System(4)'s and a few Wininit.exe's The only one in the list I know is the Chrome.exe I manually set a rule for so I could access the internet. If these ports are Blocked, then How can they be open? This is confusing and misleading to me. there is also an option to kill leading me to believe these ports are open and active with outgoing connections. Yet, if I right click on any of the ports, there is an option for UnBlock. I see under Show Connections if I have Open Ports checked, I get a list of what I presume to be, Open ports (open meaning unblocked IMO). If anyone else has any other fixes, I'll be posting them here as well.I'm using Windows 8.0 with Tinywall. And I can post it here to help other people.ĮDIT 2: A user in the comments just mentioned they fixed this by closing and reopening the tab until it worked, and it took them two tries with this method. If anyone else finds out how to fix this without using another computer, I'd love to know. It has to be some kind of software problem and Riot should seriously look into it. It seems like some computers have the issue and some don't, but I'm not sure why. Since MY computer never had this issue, I ended up just letting my friend log in on my computer instead, and he used my computer to agree to the code of conduct - and then he was able to log in on his own computer after that without issue. What could this possibly be.? How could this possibly be fixed?ĮDIT: Fixed it for my friend, at least. Instead, it just says "In the League of Legends community, I will." - followed by a bunch of blank space, and a greyed out "OK" button that he can't press until he agrees to the non-existent Code of Conduct. except there's no Code of Conduct showing up, so he can't proceed. ![]() My friend just downloaded LoL for the first time, but he just gets stuck on the "Code of conduct" screen. ![]() Live Discussion Archive AMAs Organization Schedule For LEC, LCS, LPL, and LCK Esports Wiki Pages Spoiler free Subreddit START AUTO-GENERATION, DO NOT TOUCH Upcoming Matches Match Changes to Server Status Rule Subreddit Information ![]() ![]() The opening song for the third season is "ENAMEL" by Sid, while the ending song is "Aoki Tsuki Michite" by AKIRA.Īniplex later released the complete Blu-ray and DVD on May 7, 2014. The ending for episode 8 is "Kagayaku Sora no Shijima ni wa" by Kalafina. The third single containing tracks from Kalafina has a release date of March 4, 2009.įor the second season, the opening song is "Shiver" by The Gazette and the ending song "Bird" is sung by Yuya Matsushita, and the single was released in August 2010. Two singles containing the theme music and other tracks have been released the single containing tracks from Sid was released on Octoand the single from Becca was released on October 22, 2008. The second ending, which began airing with episode 14, is "Lacrimosa" by Kalafina. The opening theme is "Monochrome no Kiss" (though written as Monochrome Kiss) by the Japanese rock band Sid, while the first ending theme is "I'm Alive!" by the American singer Rebecca Hollcraft, commonly known as Becca. Three pieces of theme music are used for the first season. The first OVA was released in Japanese cinemas on October 25, and the second on November 15, 2014. Which adapts the "Phantomhive Manor Murders" arc. The series was followed by a two-episode OVA, Black Butler: Book of Murder, Serving as a soft reboot of the anime, the series adapts the "Noah Ark Circus" arc from the manga while ignoring the anime-exclusive events of the previous two seasons. The third season, Book of Circus (黒執事・サーカスの書, Kuroshitsuji: Sākasu no Sho), premiered on July 10, 2014, and concluded on September 12, 2014. The second season, which premiered on July 2, 2010, and concluded on September 17, 2010, continues this original storyline. Īfter the sixth episode, the anime begins to diverge from the storyline of the manga. Two DVD compilations were released by Aniplex the first compilation on Januand the second on February 25, 2009. The series premiered on October 3, 2008, on Mainichi Broadcasting System and Chubu-Nippon Broadcasting. ![]() The anime adaptation was confirmed on Jby Gakken's Animedia magazine, and the official website of the anime began to stream a trailer of the anime on July 26, 2008. Directed by Toshiya Shinohara and produced by A-1 Pictures, Black Butler follows the adventures of Sebastian Michaelis, a demon butler who is obligated to serve Ciel Phantomhive, the young head of the Phantomhive noble family, due to a contract he made. The cover of the first DVD compilation released by Aniplex the characters featured are Sebastian Michaelis (left) and Ciel Phantomhive (right)īlack Butler is an anime series adapted from the manga series of the same title by Yana Toboso. ![]() |
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